2-Deoxy-2,3-O-isopropylidene-2,4-di-C-methyl-β-l-arabinose
نویسندگان
چکیده
X-ray crystallography unequivocally confirmed the stereochemistry of the C atom at position 2 in the carbon scaffold of the title mol-ecule, C(10)H(18)O(4). The pyran-ose ring exists in a chair conformation with the methyl group on the C atom in the 2 position in an equatorial configuration. The absolute stereochemistry was determined from the starting material. The crystal structure consists of O-H⋯O hydrogen-bonded chains of mol-ecules running parallel to the b axis.
منابع مشابه
3-Deoxy-1,2-di-O-isopropylidene-5-O-tosyl-d-threo-pentofuranose
In the crystal structure of the title compound, C(15)H(20)O(6)S, the two independent mol-ecules crystalllize in a chiral setting with two different conformations, twisted (4)T(3) and envelope (4)E, for the furan-ose rings. Weak C-H⋯O contacts strengthen the crystal structure.
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The polysaccharide exuded by Acacia decurrens trees contains residues of D-galactose , LArabinose , L-Fucose and Dglucuronic acid. An examination of the OMethyl derivatives of the gum yields 2,3,4,6 tetra –O-methyl –D-galactose, 2,3 –di-O-Methyl –L-arabinose , 2,3,4-triO-methyl-D-galactose, 2,4-di-O-methyl-D-galactose together with 2,3,4 tri-O-methyl-Dglucuronic acid by acid hydrolysis. The deg...
متن کامل6-Deoxy-3,4-O-isopropylidene-2-C-methyl-l-galactono-1,5-lactone
X-ray crystallography unequivocally confirmed the stereochemistry of the 2-C-methyl group in the title mol-ecule, C(10)H(16)O(5), in which the 1,5-lactone ring exists in a boat conformation. The absolute stereochemistry was determined by the use of d-ribose in the synthesis. The crystal exists as O-H⋯O hydrogen bonded chains of mol-ecules running parallel to the a axis with each mol-ecule actin...
متن کامل2-Azido-2-deoxy-3,4-O-isopropylidene-2-C-methyl-d-talono-1,5-lactone
The relative stereochemistry of the title compound, C(10)H(15)N(3)O(5), was confirmed by the crystal structure determin-ation. The absolute configuration was determined from the use of d-lyxonolactone as the starting material. The six-membered ring adopts a boat conformation with the larger azide group, rather than the methyl group, in the bowsprit position. In the crystal structure, a bifurcat...
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The reaction of 5-azido-5-de-oxy-2,3-O-isopropyl-idene-2-C-methyl-d-ribose with N,N-diethyl-2-(dimethyl-sulfuranyl-idene)acetamide gave the title compound, C(15)H(26)N(4)O(5), as the major product arising from initial formation of an epoxide which was subsequently opened by intra-molecular attack of the free 4-hydroxyl group. X-ray crystallography confirmed the relative stereochemistry of the t...
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عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2009